〔閲覧〕【著作】([平野 朋広]/Kamikubo Takahiro/Okumura Yuya/[佐藤 恒之]/Heterotactic poly(N-isopropylacrylamide) prepared via radical polymerization in the presence of fluorinated alcohols/[Polymer])
(英) Heterotactic poly(N-isopropylacrylamide) prepared via radical polymerization in the presence of fluorinated alcohols (日)
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(英) Radical polymerization of N-isopropylacrylamide in toluene at -40 °C in the presence of fourfold amounts of fluorinated alcohols was investigated. The 13C NMR analysis of the obtained polymers suggested that the addition of fluorinated alcohols induced heterotactic specificity in radical polymerization of NIPAAm, although syndiotactic poly(NIPAAm)s were obtained by adding alkyl alcohols as we have previously reported. To the best of our knowledge, this is the first synthesis of heterotactic poly(NIPAAm). (日) フッ素化アルコール存在下,N-イソプロピルアクリルアミドのラジカル重合を行うと,ヘテロタクチックポリマーが得られることを見出した.
Tomohiro Hirano, Takahiro Kamikubo, Yuya OkumuraandTsuneyuki Sato : Heterotactic poly(N-isopropylacrylamide) prepared via radical polymerization in the presence of fluorinated alcohols, Polymer, Vol.48, No.17, 4921-4925, 2007.
欧文冊子 ●
Tomohiro Hirano, Takahiro Kamikubo, Yuya OkumuraandTsuneyuki Sato : Heterotactic poly(N-isopropylacrylamide) prepared via radical polymerization in the presence of fluorinated alcohols, Polymer, Vol.48, No.17, 4921-4925, 2007.
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