〔閲覧〕【著作】([平野 朋広]/Masuda Shuhei/[佐藤 恒之]/Hydrogen-Bond-Assisted Syndiotactic-Specific Radical Polymerization of N,N-Dimethylacrylamide in the Presence of Tartrates/[Journal of Polymer Science Part A: Polymer Chemistry])
(英) Hydrogen-Bond-Assisted Syndiotactic-Specific Radical Polymerization of N,N-Dimethylacrylamide in the Presence of Tartrates (日)
[継承]
○副題(任意):
○要約(任意):
□
(英) The radical polymerizations of N,N-dimethylacrylamide (DMAAm) at low temperatures in the presence of alcohol compounds were investigated. It was found that the addition of tartrates into the DMAAm polymerizations in toluene significantly induced the syndiotactic-specificity. In addition, both the yield and the molecular weights of the obtained polymers increased with the addition of tartrates. To the best of our knowledge, this is the first example of syndiotactic-specific radical polymerization of DMAAm. (日) N,N-ジメチルアクリルアミドのラジカル重合系に酒石酸エステルを添加すると,重合反応を加速するだけでなくシンジオタクチシチシーに富むポリマーを与えることを見出した.
Tomohiro Hirano, Shuhei MasudaandTsuneyuki Sato : Hydrogen-Bond-Assisted Syndiotactic-Specific Radical Polymerization of N,N-Dimethylacrylamide in the Presence of Tartrates, Journal of Polymer Science Part A: Polymer Chemistry, Vol.46, No.9, 3145-3149, 2008.
欧文冊子 ●
Tomohiro Hirano, Shuhei MasudaandTsuneyuki Sato : Hydrogen-Bond-Assisted Syndiotactic-Specific Radical Polymerization of N,N-Dimethylacrylamide in the Presence of Tartrates, Journal of Polymer Science Part A: Polymer Chemistry, Vol.46, No.9, 3145-3149, 2008.
関連情報
Number of session users = 0, LA = 1.47, Max(EID) = 420298, Max(EOID) = 1135275.