『徳島大学 教育・研究者情報データベース (EDB)』---[学外] /
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EID=160513EID:160513, Map:0, LastModified:2013年6月7日(金) 15:13:56, Operator:[松井 栄里], Avail:TRUE, Censor:0, Owner:[[学科長]/[徳島大学.工学部.化学応用工学科]], Read:継承, Write:継承, Delete:継承.
種別 (必須): 学術論文 (審査論文) [継承]
言語 (必須): 英語 [継承]
招待 (推奨):
審査 (推奨): Peer Review [継承]
カテゴリ (推奨): 研究 [継承]
共著種別 (推奨):
学究種別 (推奨):
組織 (推奨): 1.The Scripps Research Institute [継承]
著者 (必須): 1.岩澤 哲郎
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学籍番号 (推奨):
[継承]
2. (英) Hooley Richard (日) (読)
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[継承]
3. (英) Rebek Julius (日) (読)
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[継承]
題名 (必須): (英) Stabilization of Labile Carbonyl Addition Intermediates by a Synthetic Receptor  (日)    [継承]
副題 (任意):
要約 (任意): (英) Products of unfavorable chemical equilibria are not readily observed because their high energy and increased reactivity result in low concentrations. Biological macromolecules use binding forces to access unfavorable equilibria and stabilize reactive intermediates by isolating them from the medium. In a similar vein, we describe here a synthetic receptor that allows direct observation of labile tetrahedral intermediates: hemiaminals formed in the reaction of an aldehyde carbonyl group with amines. The receptor encapsulates alkyl-substituted primary amines, then orients them toward a covalently tethered aldehyde function. The hemiaminal intermediates appear at high concentration, confined from the bulk solution and observable at ambient temperature by conventional nuclear magnetic resonance spectroscopy.  (日)    [継承]
キーワード (推奨): 1. (英) Aldehydes (日) (読) [継承]
2. (英) Amines (日) (読) [継承]
3. (英) Chemistry, Physical (日) (読) [継承]
4. (英) Diamines (日) (読) [継承]
5. (英) Ethers, Cyclic (日) (読) [継承]
6. (英) Hydrogen Bonding (日) (読) [継承]
7. (英) Imines (日) (読) [継承]
8. (英) Magnetic Resonance Spectroscopy (日) (読) [継承]
9. (英) Molecular Structure (日) (読) [継承]
10. (英) Physicochemical Phenomena (日) (読) [継承]
11. (英) Resorcinols (日) (読) [継承]
12. (英) Thermodynamics (日) (読) [継承]
発行所 (推奨): (英) American Association for the Advancement of Science (日) (読) [継承]
誌名 (必須): Science (The American Association for the Advancement of Science)
(pISSN: 0036-8075, eISSN: 1095-9203)

ISSN (任意): 1095-9203
ISSN: 0036-8075 (pISSN: 0036-8075, eISSN: 1095-9203)
Title: Science (New York, N.Y.)
Title(ISO): Science
Publisher: Amer. Assoc. Adv. Sci., Washington, DC.
 (NLM Catalog  (Scopus  (CrossRef (Scopus information is found. [need login])
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(必須): 317 [継承]
(必須): 5837 [継承]
(必須): 493 496 [継承]
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年月日 (必須): 西暦 2007年 7月 27日 (平成 19年 7月 27日) [継承]
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DOI (任意): 10.1126/science.1143272    (→Scopusで検索) [継承]
PMID (任意): 17656719    (→Scopusで検索) [継承]
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WOS (任意): 000248339800039 [継承]
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備考 (任意): 1.(英) Article.Affiliation: Skaggs Institute for Chemical Biology and Department of Chemistry, Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, CA 92037, USA.  (日)    [継承]
2.(英) Article.PublicationTypeList.PublicationType: Journal Article  (日)    [継承]
3.(英) Article.PublicationTypeList.PublicationType: Research Support, N.I.H., Extramural  (日)    [継承]
4.(英) Article.PublicationTypeList.PublicationType: Research Support, Non-U.S. Gov't  (日)    [継承]

標準的な表示

和文冊子 ● Tetsuo Iwasawa, Richard Hooley and Julius Rebek : Stabilization of Labile Carbonyl Addition Intermediates by a Synthetic Receptor, Science, Vol.317, No.5837, 493-496, 2007.
欧文冊子 ● Tetsuo Iwasawa, Richard Hooley and Julius Rebek : Stabilization of Labile Carbonyl Addition Intermediates by a Synthetic Receptor, Science, Vol.317, No.5837, 493-496, 2007.

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