『徳島大学 教育・研究者情報データベース (EDB)』---[学外] /
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登録内容 (EID=136262)

EID=136262EID:136262, Map:0, LastModified:2006年3月2日(木) 12:01:01, Operator:[南川 慶二], Avail:TRUE, Censor:0, Owner:[南川 慶二], Read:継承, Write:継承, Delete:継承.
種別 (必須): 国際会議 [継承]
言語 (必須): 英語 [継承]
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審査 (推奨): Peer Review [継承]
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組織 (推奨): 1.徳島大学.工学部.化学応用工学科.物質合成化学講座 [継承]
著者 (必須): 1.森 健
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2.南川 慶二 ([徳島大学.教養教育院])
役割 (任意): 共著 [継承]
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3.田中 正己 ([徳島文理大学])
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[継承]
題名 (必須): (英) Polymerization of Diacetylene Using β-Sheet as a Template  (日)    [継承]
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要約 (任意): (英) β-sheet which is one of the secondary structures of peptide was applied to the template for polymerization of diacetylene. To test the applicability of the β-sheet, the diacetylene modified tyrosine (1) was synthesized. It was confirmed by IR measurements that 1 formed parallel β-sheet-like structure in crystalline state. The polymerization proceeded upon UV irradiation or heating of the crystal. It was revealed that the polymerization proceeded via a crystal-to-crystal process. The polymerized 1 was insoluble in common organic solvents except for trifluoroacetic acid and dichloroacetic acid. The limited solubility of the polymerized 1 indicated that there is a strong hydrogen bonding interaction among the monomeric units of the polydiacetylene along the polymer strand. Next, the polymerization of diacetylene was examined in oligopeptides. The diacetylene modified threonine was introduced in the center of 11mer peptide that was designed to form anti-parallel b-sheet. In the b-sheet formed from the peptide, polymerization of diacetylene successfully proceeded.  (日)    [継承]
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誌名 (必須): (英) The 4th International Conference on Advanced Materials Development and Performace (日) (読)
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都市 (必須): オークランド (Auckland/[ニュージーランド]) [継承]
年月日 (必須): 西暦 2005年 7月 12日 (平成 17年 7月 12日) [継承]
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標準的な表示

和文冊子 ● Takeshi Mori, Keiji Minagawa and Masami Tanaka : Polymerization of Diacetylene Using β-Sheet as a Template, The 4th International Conference on Advanced Materials Development and Performace, (巻), (号), (頁), Auckland, July 2005.
欧文冊子 ● Takeshi Mori, Keiji Minagawa and Masami Tanaka : Polymerization of Diacetylene Using β-Sheet as a Template, The 4th International Conference on Advanced Materials Development and Performace, (巻), (号), (頁), Auckland, July 2005.

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