徳島大学 教育・研究者情報データベース(EDB)

1. 徳島大学.大学院社会産業理工学研究部.理工学域.応用化学系.化学プロセス工学分野(2017年4月1日〜)
2. 徳島大学.先端技術科学教育部.物質生命システム工学専攻.化学機能創生コース.化学プロセス工学講座(2012年4月1日〜)

1. 杉山 茂

   役割	任意
   貢献度	任意
   学籍番号	推奨

2. (英) Sakuwa Yasuhiro / (日) 佐桑 康太 / (読) さくわ やすひろ

   役割	任意
   貢献度	任意
   学籍番号	推奨	****

3. (英) Ogino Tomoyasu / (日) 荻野 友保 / (読) おぎの ともやす

   役割	任意
   貢献度	任意
   学籍番号	推奨	****

4. (英) Sakamoto Naotaka / (日) 坂本 尚隆 / (読) さかもと なおたか

   役割	任意
   貢献度	任意
   学籍番号	推奨	****

5. 霜田 直宏([徳島大学.大学院社会産業理工学研究部.理工学域.応用化学系.化学プロセス工学分野]/徳島大学.理工学部.理工学科.応用化学システムコース.化学プロセス工学講座/徳島大学.工学部.化学応用工学科.化学プロセス工学講座/徳島大学.先端技術科学教育部.物質生命システム工学専攻.化学機能創生コース.化学プロセス工学講座)

   役割	任意
   貢献度	任意
   学籍番号	推奨

6. 加藤 雅裕([徳島大学.大学院社会産業理工学研究部.理工学域.応用化学系.化学プロセス工学分野]/[徳島大学.理工学部.理工学科.応用化学システムコース.化学プロセス工学講座])

   役割	任意
   貢献度	任意
   学籍番号	推奨

7. (英) Kimura Nobuhiro / (日) 木村 信啓 / (読) きむら のぶひろ

   役割	任意
   貢献度	任意
   学籍番号	推奨

(英) Gas Phase Epoxidation of Propylene to Propylene Oxide on a Supported Catalyst Modified with Various Dopants

(日) 様々な添加物で修飾した担持触媒によるプロピレンからプロピレンオキサイドへの気相エポキシ化

(英) In the present study, the production of propylene oxide (PO) from propylene via gas phase epoxidation was investigated using various catalysts. Although Ag is known to be a highly active catalyst for the epoxidation of ethylene, it was not active in the present reaction. Both Al and/or Ti showed high level of activity, however, which resulted in confusion. The present study was conducted to solve such confusion. The intent of the present study was to solve such confusion. Although the employment of MCM 41 modified with Ti and/or Al was reported as an active catalyst for epoxidation, the combination resulted in a formation of PO that amounted to less than a 0.1% yield. Since this research revealed that the acidic catalyst seemed favorable for the formation of PO, versions of ZSM 5 that were both undoped and doped with Na, Ti and Ag were used as catalysts. In these cases, small improvements of 0.67 and 0.57% were achieved in the PO yield on H ZSM 5 and Ti ZSM 5. Based on the results of the Ti dopant and acidic catalysts, Ag metal doped on carbonate species with a smaller surface area was used as a catalyst. As reported, Ag Na/CaCO3 showed a greater yield of PO at 1.29%. Furthermore, the use of SrCO3 for CaCO3 resulted in a further improvement in the PO yield to 2.17%. An experiment using CO2 and NH3 pulse together with SEM and TEM examinations for Ag Na/CaCO3 revealed that the greatest amount of activity was the result of the greater particle size of metallic Ag rather than the acid base properties of the catalysts.